IB Chemistry · S3.2 · HL

S3.2 Functional groups: Classification of organic compounds (HL)

15 revision questions with answers for S3.2 Functional groups: Classification of organic compounds (HL). Read them here, or play the set as a class game on the projector. Free to host, and students join with a code.

A question from this set

Isomers with the same structural formula but different spatial arrangement of atoms?

  • StereoisomersRight answer
  • Structural isomers
  • Homologues
  • Tautomers
From S3.2 Functional groups: Classification of organic compounds (HL), 15 questions.

What this set covers

Organic structure at HL: stereoisomerism, chiral carbons, enantiomers, racemic mixtures and the polarimeter, cis-trans isomers of but-2-ene, and splitting patterns in ¹H NMR using the n + 1 rule.

Common mix-up
Students often mix up cis-trans isomers and enantiomers: cis-trans isomerism comes from restricted rotation about C=C, while enantiomers come from a chiral carbon.
Revision tip
Draw butan-2-ol with its four different groups marked, then apply the n + 1 rule to predict the splitting for each proton environment in ethanal.

All 15 questions and answers

  1. Isomers with the same structural formula but different spatial arrangement of atoms?

    Answer: Stereoisomers

  2. Carbon atom bonded to four different groups?

    Answer: Chiral carbon

  3. Non-superimposable mirror-image molecules?

    Answer: Enantiomers

  4. Equimolar mixture of two enantiomers?

    Answer: Racemic mixture

  5. Instrument that measures the angle by which an optically active sample rotates light?

    Answer: Polarimeter

  6. Two enantiomers rotate plane-polarised light by equal angles but…?

    Answer: In opposite directions

  7. Isomer of CH₃CH=CHCH₃ with both methyl groups on the same side?

    Answer: cis-but-2-ene

  8. Cis-trans isomerism in alkenes arises from restricted rotation about which bond?

    Answer: C=C bond

  9. Which of these alcohols is chiral?

    Answer: Butan-2-ol

  10. Number of chiral carbons in CH₃CHClCH₂CH₃?

    Answer: 1

  11. Rule predicting peaks in a ¹H NMR signal split by n neighbouring protons?

    Answer: n + 1 rule

  12. ¹H NMR splitting of a proton with three H atoms on the adjacent carbon?

    Answer: Quartet

  13. ¹H NMR splitting of the CH₃ signal in an ethyl group, CH₃CH₂–?

    Answer: Triplet

  14. ¹H NMR splitting of the CH₃ signal in ethanal, CH₃CHO?

    Answer: Doublet

  15. ¹H NMR splitting of a proton with no H atoms on adjacent carbons?

    Answer: Singlet

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